Collision theory — Science definition

The model that reactions happen only when particles collide with enough energy and the correct orientation.

Where it is taught

In use

To understand what sets that speed, chemists use collision theory.

Reaction Rates & Kinetics

Questions using collision theory

Problem 1

According to collision theory, an effective collision requires…
  1. enough energy and the correct orientation
  2. that a catalyst be present
  3. that the reaction be exothermic
  4. only that the particles touch
Answer and explanation

enough energy and the correct orientation

A collision only produces a reaction if the particles collide with at least the activation energy and are properly oriented.

Problem 2

Explain, using collision theory, why powdered zinc reacts with acid much faster than a single lump of zinc of the same mass.
Answer and explanation

Powder has far more exposed surface area than a single lump, so many more zinc atoms are in contact with the acid at once. That allows far more effective collisions per second between zinc and acid particles, which speeds up the reaction.

Problem 3

Using collision theory, explain why increasing the concentration of a reactant speeds up a reaction.
Answer and explanation

Higher concentration packs more reactant particles into the same volume, so collisions between particles happen more often. More collisions per second means more effective collisions per second, which speeds up the reaction.

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