Formal charge — Science definition

An electron-counting assignment, distinct from partial charge.

Where it is taught

In use

Formal charge is bookkeeping: valence electrons minus nonbonding electrons minus half of bonding electrons.

Lewis Structures, Resonance & Bond Models

Questions using formal charge

Problem 1

For NH₄⁺, count valence electrons, assign nitrogen’s formal charge for four N–H single bonds and no lone pair, and distinguish that charge from molecular shape.
Answer and explanation

Total valence electrons are 5+4(1)−1=8. Nitrogen formal charge is 5−0−4=+1 and each H is zero. The flat Lewis connectivity does not specify measured angles; the common molecular arrangement is tetrahedral.

Total valence electrons are 5+4(1)−1=8. Nitrogen formal charge is 5−0−4=+1 and each H is zero. The flat Lewis connectivity does not specify measured angles; the common molecular arrangement is tetrahedral.

Response criteria

  • Use the stated measurements or conditions, with correct units.
  • Connect the result to the chemical mechanism or evidence relationship.
  • Identify the assumption, model limit or further evidence requested.

Problem 2

Independent chapter check: For NH₄⁺, count valence electrons, assign nitrogen’s formal charge for four N–H single bonds and no lone pair, and distinguish that charge from molecular shape.
Answer and explanation

Total valence electrons are 5+4(1)−1=8. Nitrogen formal charge is 5−0−4=+1 and each H is zero. The flat Lewis connectivity does not specify measured angles; the common molecular arrangement is tetrahedral.

Total valence electrons are 5+4(1)−1=8. Nitrogen formal charge is 5−0−4=+1 and each H is zero. The flat Lewis connectivity does not specify measured angles; the common molecular arrangement is tetrahedral.

Response criteria

  • Use the stated measurements or conditions, with correct units.
  • Connect the result to the chemical mechanism or evidence relationship.
  • Identify the assumption, model limit or further evidence requested.

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