Valence electrons — Science definition

Electrons relevant to the chemical bonding model. Main-group outer-shell patterns are a useful case; transition elements can involve nearby d states.

Where it is taught

In use

For main-group elements, valence electrons are usually the electrons in the outermost occupied shell.

Electron Configuration

Questions using valence electrons

Problem 1

Bromine (Z = 35) has the configuration [Ar] 4 s² 3d¹⁰ 4p⁵. How many valence electrons does it have?
Answer and explanation

7

Valence electrons are those in the highest energy level (n = 4): 4 s² + 4p⁵ = 7. The inner 3d¹⁰ electrons are core, not valence.

Problem 2

Sulfur's configuration is 1 s² 2 s² 2p⁶ 3 s² 3p⁴. How many valence electrons does it have?
Answer and explanation

6

Valence electrons are those in the highest level (n = 3): 3 s² 3p⁴ = 6.

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