VSEPR theory — Science definition

Valence Shell Electron Pair Repulsion — the idea that electron groups around a central atom spread out as far apart as possible, which sets the molecule's shape.

Where it is taught

In use

The tool chemists use to predict that shape from a simple Lewis structure is VSEPR theory, which stands for Valence Shell Electron Pair Repulsion — a long name for one commonsense idea.

Molecular Geometry & Polarity

Questions using vsepr theory

Problem 1

VSEPR theory predicts molecular shape based on the idea that the electron groups around a central atom…
  1. always stay at fixed 90° angles
  2. have no effect on the shape
  3. attract each other
  4. repel and spread as far apart as possible
Answer and explanation

repel and spread as far apart as possible

Electron groups are all negative, so they repel and spread out as far as possible, which sets the shape.

Problem 2

VSEPR theory is used to predict a molecule's…
  1. mass
  2. temperature
  3. color
  4. three-dimensional shape
Answer and explanation

three-dimensional shape

VSEPR predicts molecular shape from how electron groups repel and spread out.

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