Metallic Bonding — Practice · Grade 11 Science
Chapter: Bonding, Formulas & Molecular StructureWhat this practice covers
By the end of Metallic Bonding you should be able to:
- I can describe metallic bonding using the electron-sea model of positive ions in a shared pool of delocalized electrons.
- I can use the electron-sea model to explain metals' conductivity, malleability, ductility, and luster.
10 questions, multiple choice and written answer, each with a worked explanation.
Vocabulary used: metallic bond, delocalized electrons, electron sea, malleable, ductile, luster, alloy.
Problem 1
- separate molecules sharing electron pairs
- neutral atoms locked rigidly in place
- positive ions surrounded by mobile, delocalized electrons
- negative ions in a fixed lattice
Answer and explanation
positive ions surrounded by mobile, delocalized electrons
Metals form positive ions that sit in a shared sea of freely moving delocalized electrons.
Problem 2
- low density
- transparency
- brittleness
- electrical conductivity
Answer and explanation
electrical conductivity
Free-moving electrons can drift under a voltage, carrying an electric current, so metals conduct electricity.
Problem 3
- Their ions can slide past one another while the electron sea keeps holding them together
- Their bonds are rigid and point in fixed directions
- They contain no electrons to get in the way
- They are made of separate small molecules
Answer and explanation
Their ions can slide past one another while the electron sea keeps holding them together
When struck, layers of metal ions shift, but the mobile electron sea flows with them and keeps the metal bonded, so it bends instead of breaking.
Problem 4
Answer and explanation
In ionic bonding, electrons are fully transferred from a metal to a nonmetal, creating positive and negative ions locked in a rigid lattice. In metallic bonding, the metal atoms' valence electrons are not transferred to any single atom but are shared among all of them in a mobile 'sea,' so the electrons stay free to move and the bond reaches in every direction.
Problem 5
- its rigid ionic lattice
- the free electrons absorbing and re-emitting light
- the metal's very high density
- electrons that are tightly bound to each atom
Answer and explanation
the free electrons absorbing and re-emitting light
The delocalized electrons readily absorb light and re-emit it, reflecting it back to give a shiny surface.
Problem 6
- Salt is much softer than copper
- Copper is actually a gas at room temperature
- Copper's electron sea lets layers of ions shift while staying bonded, but shifting an ionic lattice aligns like charges that repel and split it
- Copper contains no chemical bonds at all
Answer and explanation
Copper's electron sea lets layers of ions shift while staying bonded, but shifting an ionic lattice aligns like charges that repel and split it
The mobile electron sea holds shifting metal ions together, while in an ionic solid a shifted layer brings like charges together, and they repel and cleave the crystal.
Problem 7
Hints
A model explains trends, but real alloys and structures affect behavior.
Answer and explanation
It has mobile delocalized electrons; ordinary ionic solids lack comparably mobile ions.
Problem 8
Hints
State what the supplied observations or conditions establish, and separate that from any assumption.
Answer and explanation
No. Composition, crystal structure, defects and processing affect mechanical properties.
Problem 9
Answer and explanation
The substitutional species replaces a host-site occupant; the interstitial species occupies a space between host sites in the simplified arrangement.
An alloy combines a metallic element with one or more other elements. In a substitutional model, some host sites are occupied by another species; in an interstitial model, smaller atoms occupy spaces between selected host sites. Both can influence dislocation motion and properties. Real alloys may include several phases and complex microstructures, so a uniform dot pattern is not a universal atom-by-atom picture. State composition, treatment and measured property before recommending an alloy for a design.
The substitutional species replaces a host-site occupant; the interstitial species occupies a space between host sites in the simplified arrangement.
Response criteria
- Interpret labels, structures, axes, units and directions correctly.
- Explain the chemistry relationship or mechanism.
- Respect stated assumptions and distinguish observation from inference.
Problem 10
Answer and explanation
P satisfies both stated constraints. Q fails conduction and R fails strength. Cost, corrosion, fatigue, fabrication or service temperature could still change the decision.
P satisfies both stated constraints. Q fails conduction and R fails strength. Cost, corrosion, fatigue, fabrication or service temperature could still change the decision.
Response criteria
- Use the stated measurements or conditions, with correct units.
- Connect the result to the chemical mechanism or evidence relationship.
- Identify the assumption, model limit or further evidence requested.